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[1]李立,王光华*,高祥,等.含功能性单体引发剂在微乳液中合成PAM的研究[J].武汉工程大学学报,2008,(03):28-32.
 LI Li,WANG Guang hua,GAO Xiang,et al.Study on synthesis of polyacrylamide in microemulsion by initiator containing functional monomer[J].Journal of Wuhan Institute of Technology,2008,(03):28-32.
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含功能性单体引发剂在微乳液中合成PAM的研究(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2008年03期
页码:
28-32
栏目:
化学与化学工程
出版日期:
2008-03-31

文章信息/Info

Title:
Study on synthesis of polyacrylamide in microemulsion
by initiator containing functional monomer
文章编号:
16742869(2008)03002904
作者:
李立12王光华12*高祥12陈辉刚1李蕾3李文兵12
1.武汉科技大学化学工程与技术学院,湖北 武汉 430081;2.湖北省煤转化与新型炭材料
重点实验室,湖北 武汉 430081;3.武汉工程大学分析测试中心,湖北 武汉 430074
Author(s):
LI Li12WANG Guanghua12GAO Xiang12CHEN Huigang1LI Lei3LI Wenbing12
1. College of Chemical Engineering and Technology,Wuhan University of Science and Technology,Wuhan 430081,China;
2. Hubei Key Laboratory of Coal Conversion and New Carbon Materials,Wuhan 430081,China;
3. Center of Analysis and Test, Wuhan Institute of Technology,Wuhan 430074,China
关键词:
聚丙烯酰胺功能性单体反相微乳液表征
Keywords:
PAM functional monomer inverse microemulsion characterization
分类号:
TQ325.114
DOI:
-
文献标志码:
A
摘要:
采用含功能性单体的氧化还原引发剂在反相微乳液中合成聚丙烯酰胺.正交试验的结果表明,功能性单体与还原剂的质量比和反应温度是影响聚丙烯酰胺分子量的主要因素.实验得到的最佳反应条件如下:单体浓度为30%,反应温度为30℃,引发剂浓度为0.15%,功能性单体与还原剂的质量比为0.25,在此条件下合成的聚丙烯酰胺的相对分子量为1.09×107.采用傅立叶红外光谱仪对合成的聚丙烯酰胺进行了表征.
Abstract:
A kind of redox initiator containing functional monomer was used to synthesize polyacrylamide through inverse microemulsion,and the result of the orthogonal experiments showed that mfunctional monomer/mreductant(the mass ratio) and the reaction temperature were the major factors which affected the molecularweight of polyacrylamide.The optimal reaction conditions were as follows:monomer mass concentration was 30%,the reaction temperature was 30℃,the initiator mass concentration was 0.15%,mfunctional monomer/mreductant was 0.25.The molecularweight of polyacrylamide with 1.09 × 107 was synthesized under this optimal conditions.FTTR spectrum had been used to characterize the synthesised PAM.

参考文献/References:

[1]Shalaby W,McCormick C L.watersoluble Polymers Synthesis,Solution Properties and Applications[M].Washington D.C:American Chemical Society,1991:2.
[2]方道斌,郭睿威,哈润华,等.丙烯酰胺聚合物[M].北京:化学工业出版社,2006:9.
[3]高青雨,关会立,李润明,等.3甲基丙烯酰胺基9乙基咔唑/过硫酸钾体系引发丙烯酰胺聚合[J].化学研究,2000,11(3):1820.
[4]张贞浴,祖春兴,乔丽艳.含胺基功能性单体的聚合研究ⅩⅣ.含二甲基丙烯酰类衍生物与过硫酸钾引发体系引发的丙烯酰胺聚合[J].高分子学报,1990,(5):623627.
[5]张贞浴,潘桂兰,赵延庆,等.过硫酸盐—含叔胺单体—亚硫酸氢钠复合引发体系引发丙烯酰胺聚合动力学研究[J].黑龙江大学自然科学学报,1997,14(1):102104.
[6]GB175141998,水处理剂聚丙烯酰胺[S].

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备注/Memo

备注/Memo:
收稿日期:20080114
作者简介:李立(1983),女,河南新乡人,硕士研究生.研究方向:精细化学品合成.
指导老师:王光华,教授,硕士生系师.研究方面:精细化学品合成及废水处理.*通信联系人
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