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[1]郭雅妮*,何俭,骆沛尧.高折射率环氧树脂的研究进展[J].武汉工程大学学报,2014,(07):53-58.[doi:103969/jissn16742869201407011]
　GUO Ya ni,HE Jian,LUO Pei yao.Research progress of high refractive index epoxy resin[J].Journal of Wuhan Institute of Technology,2014,(07):53-58.[doi:103969/jissn16742869201407011]
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高折射率环氧树脂的研究进展(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2014年07期
页码:
53-58
栏目:
材料科学与工程
出版日期:
2014-07-31

文章信息/Info

Title:
Research progress of high refractive index epoxy resin
文章编号:
16742869(2014)07005306
作者:
郭雅妮*;  何俭; 骆沛尧
武汉工程大学材料科学与工程学院，湖北 武汉430074
Author(s):
GUO Yani;  HE Jian;  LUO Peiyao
School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
光学树脂; 环氧; 制备方法; 高折射率
Keywords:
optical resins; epoxy; preparation method; high refractive index
分类号:
TQ323.5
DOI:
103969/jissn16742869201407011
文献标志码:
A
摘要:
高折射率环氧光学树脂设计制备方法主要包括三类：通过有机或无机化合物在环氧光学树脂中引入硫、卤素等高折光指数原子；在环氧光学树脂中引入芳环等高折光指数化学基团；由两种或两种以上的环氧树脂混合固化来制备复合型环氧光学树脂.现有的环氧光学树脂具有收缩率低、化学性质稳定、尺寸稳定性高等优点，但耐候性差，在紫外光的照射下会发黄降解，韧性差而易断裂，硬度不佳在树脂表面易产生划痕等缺点制约了其在更先进领域的应用.制约环氧光学树脂发展的主要因素为材料结构与性能之间的关系不够明确，制备方法不够经济环保以及过于关注材料的折光指数而对其他性能研究较少.进一步明确材料结构与性能之间的关系，在保证高折射率的前提下，平衡材料的其他光学和力学性能是未来研究的重点.
Abstract:
There are three types of methods to design and prepare epoxy optical resins with high refractive index: epoxy optical resins are prepared by organic or inorganic compounds containing high refractive index atoms such as sulfur and halogen, or by compounds with high refractive index chemical groups such as aryl; composite epoxy optical resins are prepared by mixing two or more of the epoxy resins. The existing epoxy optical resins have advantages of low shrinkage, great chemical resistance and dimensional stability, but their brittle nature, low hardness, weather resistance and degradation under ultraviolet restrict their application in some advanced fields. The factors which restrict development of the epoxy optical resins are not completely clear relationship between structures and properties, uneconomic and unfriendly preparation methods for environment and too much research on the materials’ refractive index but too little on other properties. Thus, the study of getting the balance between other optical properties and mechanical properties of the materials upon the high refractive index should be paid more attention in the future.

参考文献/References:

［1］杨柏，吕长利，沈家骢. 高性能聚合物光学材料［M］. 北京: 化学工业出版社，2005：325.YANG Bai，L Changli，SHENG Jiacong. High performance polymer optical materials［M］. Beijing：Chemical Industry Press，2005：325. (in Chinese)［2］郭雅妮. 基于环三磷腈的无卤阻燃光学树脂的制备与性能［D］. 武汉:华中科技大学，2011.GUO Yani. Preparation and properties of cyclotriphosphazenebased halogenfree flame resistance optical resins［D］. Wuhan：Huazhong University of Science & Technology，2011. (in Chinese)［3］CHIU Y，TSAI H，CHOU I，et al. Preparation，intermolecular motion，and thermal properties of thiodiphenyl epoxy ［J］. Journal of Applied Polymer Science，2010，118：21162125.［4］KREVELEN D, NIJENHUIS K. Properties of polymers ［M］. 3rd. New York: Elsevier Sciences，1991:290.［5］GAO C，YANG B，SHEN J. Study on syntheses and properties of 2,2′mercaptoethylsulfide dimethacrylate transparent homo and copolymer resins having high refractive index ［J］. Journal of Applied Polymer Science，2000，75 (12)：14741479.［6］REN H，GAO C，CUI Z，et al. Syntheses of new type of high quality optical resin ［J］. SPIE Proceeding Series，1998，8996.［7］杨柏，袁年武，高长有，等. 聚醚砜单烯大分子单体的合成与表征及其共聚物的光学特性［J］. 高分子学报，1994 (6)：659665.YANG Bai，YUAN Nianwu，GAO Changyou，et al. The synthesis and characterization of monovinylpolyethersulfones macromer and the optical properties of its copolymer［J］. Acta Polymerica Sinica，1994(6)：659665.（in Chinese）［8］曹根庭，贺建有. 高折射光学树脂单体合成技术及应用研究［J］. 工程塑料应用，2009，37 (8):5659.CAO Genting，HE Jianyou. Study on synthetic technology and application of optical resins monomer with high refractive index ［J］. Engineering Plastics Application，2009，37 (8)：5659.(in Chinese)［9］LIUB J，UEDA M. High refractive index polymers：fundamental research and practical applications ［J］. Journal of Materials Chemistry，2009，19：8907–8919.［10］YUWONO A H，LIU B，XUE J，et al. Controlling the crystallinity and nonlinear optical properties of transparent TiO2PMMA nanohybrids ［J］. Journal of Materials Chemistry，2004，14：29782987.［11］吕长利，崔占臣，杨柏. 高折射率环氧和环硫型光学树脂的研究进展［J］. 应用化学，2001，18 (5)：342346.L Changli，CUI Zhanchen，YANG Bai. Developments of epoxy and episulfidetype optical resins with high refractive index ［J］.Chinese Journal of Applied Chemistry，2001，18(5)：342346. (in Chinese)　［12］张汇萌. 双酚S环氧树脂及其衍生物的合成、结构及性能研究［D］. 北京：北京化工大学，2012.ZHANG Huimeng. Study on the bisphenol S epoxy resin and its derivatives ［D］.Beijing：Beijing University of Chemical Technology，2012. (in Chinese)［13］汪山献松，陈国贵. 光学树脂材料综述［J］. 中国眼镜科技杂志，2010(1):6061.［14］TERUYUKI NAGATA，KOJU OKAZAKI，TOHRU MIURA. Lens comprising a resin having a large refractive index and process for preparing the lens:CN1039429A (EP351073)，［P］.19900207.［15］LUO C，ZUO J，ZHAO J. Synthesis and property of epoxy prepolymer and curing agent with high refractive index［J］. High Performance Polymers，2013，25：986991.［16］TSUZUKI T. Abnormal transmittance of refractive index modified ZnO/O rganic hybrid films ［J］. Macromolecular Materials and Engineering，2008，293：109113.［17］张国彦，张纪斌，杨柏. 高折射率聚合物无机纳米光学杂化材料的设计与制造及其应用［J］. 高分子学报，2013(5)：589599.ZHANG Guoyan，ZHANG Jibin，YANG Bai. Design and fabrication of high refracrive index polymerinoganic optical hybrid materials and their practical applications ［J］. Acta Polymerica Sinica，2013(5)：589599.（in Chinese） ［18］林喆. 高折射率硫化锌/含硫聚合物纳米复合光学材料［D］. 长春：吉林大学，2011.LIN Zhe. ZnS/sulfurcontaining polymer nanocomposite optical materials with high refractive index ［D］. Changchun：Jilin University，2011. (in Chinese)［19］PALIK E D. Handbook of optical constants of solids［M］. New York ：Academic Press，1985.［20］FRENCH R H，GLASS S J，OHUCHI F S，et al. Experimental and theoretical determination of the electronic structure and optical properties of three phases of ZrO2 ［J］. Physical Review B：Condensed Matter and Materials Physics，1994，49，51335142. ［21］DEMIR M M，MEMESA M，CASTIGNOLLES P. PMMA/Zinc oxide nanocomposites prepared by insitu bulk polymerization ［J］. Macromolecular Rapid Communication，2006，27：763770.［22］KROGMAN K C，DRUFFEL T，SUNKARA M K.Antireflective optical coatings incorporating nanoparticles ［J］ .Nanotechnology， 2005，16：S338S343.［23］YIN Y，ZHOU S，GU G，et al. Preparation and properties of UVcurable polymer/nanosized indiumdoped tin oxide (ITO) nanocomposites coatings ［J］. J Mater Sci，2007，42：59595963.［24］SCHULZ H，MADLER L，PRATSINIS S E，et al. Transparent nanocomposites of radiopaque，flamemade Ta2O5/SiO2 particles in an acrylic matrix ［J］. Advanced Functional Materials，2005，15 (5)：830837.［25］YANG H L，QUAN R，ZHANG G H. Preparation and optical constants of the nanocrystal and polymer composite Bi4Ti3O12/PMMA thin films［J］. Optics and Laser Technology，2005，37，259264.［26］MATAKI H，YAMAKI S，FUKUI T. Nanostructured organic/inorganic composites as transparent materials for optical components ［J］. Japanese Journal of Applied Physics，2004，43：58195823.［27］LIU Y F，LV C L，LI M J，et al.High refractive index organic–inorganic hybrid coatings with TiO2 nanocrystals ［J］. Colloids and Surfaces A：Physicochemical and Engineering Aspects，2008，328：6772.［28］LIU B T，TANG S J，YU Y Y，et al. Highrefractiveindex polymer/inorganic hybrid films containing high TiO2 contents ［J］. Colloids and Surfaces A：Physicochemical and Engineering Aspects，2011，377：138143.［29］KOBAYASHIA M，SAITO H，BOURY B，et al. Epoxybased hybrids using TiO2 nanoparticles prepared via a nonhydrolytic sol–gel route ［J］. Applied Organ metallic Chemistry，2013，27：673677.［30］郑武成，韩娅娟，查立豫，等. 一种新型光学材料—E A 光学塑料的研制［J］. 北京理工大学学报，1993，13 (4):480484.ZHENG Wucheng，HAN Yajuan，ZHA Liyu，et al. A new optical materialthe EA optical plastics ［J］. Journal of Beijing Institute of Technology，1993，13(4)：480484. (in Chinese)［31］NAGATA，TERUYUKI. Epoxy resin lenses and their manufacture: JP 01213602 ［P］.19890828. ［32］HIMMELHUBER R，GANGOPADHYAY P，NORWOOD R A，et al. Titanium oxide solgel films with tunable refractive index［J］. Optical Society of America，2011，1：252258.［33］李永杰，张贤顺，王涛. 含苯基脂环型环氧有机硅预聚体的制备及其光固化［J］. 辐射研究与辐射工艺学报，2013，31 (1)：01030210103025.LI Yongjie，ZHANG Xianshun，WANG Tao. Preparation and UV curing of phenyl cycloaliphatic epoxysilicone oligomers ［J］.Journal of Radiation Research and Radiation Processing，2013，31(1)：01030210103025. (in Chinese)［34］郑武城，李宗禹，李永锋. 复合环氧树脂光学塑料［J］. 光学技术，1988，14 (2):3438.ZHENG Wucheng，LI Zongyu，LI Yongfeng. Epoxy composite optical plastics ［J］.Optical Technique，1988，14(2)：3438. (in Chinese)［35］吕长利，崔占臣，赵冬雪，等. 新型复合环氧光学树脂的制备与性能研究［J］. 高等学校化学学报，2001，22 (11)：19241928. L Changli，CUI Zhanchen，ZHAO Dongxue， et al. Preparation and property study of novel composite epoxytype optical resins ［J］. Chemical Journal of Chinese Universities，2001，2(11)：19241928. (in Chinese)

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备注/Memo

备注/Memo:
收稿日期：20140509基金项目：湖北省自然科学基金（2012FFC10501）；地方高校国家级大学生创新创业训练计划项目（201310490006）；武汉工程大学科学研究基金作者简介：郭雅妮（1975），女，山东平度人，副教授，博士．研究方向：功能高分子材料．*通信联系人
更新日期/Last Update: 2014-08-20