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[1]陈霖进,熊惠之,喻湘华,等.聚吡咯纳米管对抗坏血酸的电化学检测[J].武汉工程大学学报,2018,40(02):132-137.[doi:3969/j. issn. 1674?2869. 2018. 02. 003]
　CHEN Linjin,XIONG Huizhi,YU Xianghua,et al.Electrochemical Detection of Ascorbic Acid by Polypyrrole Nanotubes[J].Journal of Wuhan Institute of Technology,2018,40(02):132-137.[doi:3969/j. issn. 1674?2869. 2018. 02. 003]
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聚吡咯纳米管对抗坏血酸的电化学检测(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
40
期数:
2018年02期
页码:
132-137
栏目:
化学与化学工程
出版日期:
2018-05-17

文章信息/Info

Title:
Electrochemical Detection of Ascorbic Acid by Polypyrrole Nanotubes
文章编号:
20180203
作者:
陈霖进; 熊惠之; 喻湘华; 李　亮*
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
CHEN Linjin;  XIONG Huizhi;  YU Xianghua;  LI Liang*
School of Materials Science and Engineering， Wuhan Institute of Technology， Wuhan 430205， China
关键词:
聚吡咯纳米管;  甲基橙;  软模板;  抗坏血酸;  电化学传感器
Keywords:
polypyrrole nanotubes;  methyl orange;  soft template;  ascorbic acid;  electrochemical sensors
分类号:
O633
DOI:
3969/j. issn. 1674?2869. 2018. 02. 003
文献标志码:
A
摘要:
为了改善导电聚吡咯对于抗坏血酸的电化学检测性能，采用以甲基橙为软模板，制备了聚吡咯纳米管。利用扫描电子显微、红外光谱、X射线衍射、X射线光电子能谱对产物的结构与微观形貌进行了表征。分别将聚吡咯纳米管与聚吡咯纳米颗粒对抗坏血酸进行电化学检测。循环伏安测试结果表明，聚吡咯纳米管和聚吡咯纳米颗粒对于抗坏血酸都有明显的电化学响应，同时聚吡咯纳米管的比聚吡咯纳米颗粒的响应电流更大，表明聚吡咯纳米管具有更好的电化学检测能力。差分脉冲伏安法研究发现抗坏血酸浓度在0.5 mmol/L~20 mmol/L和20 mmol/L~45 mmol/L范围内，与峰值电流呈良好的线性关系。这表明聚吡咯纳米管作为电化学传感器材料有很好的应用前景。
Abstract:
To improve the electrochemical performance of conducting polypyrrole for sensing ascorbic acid， the polypyrrole nanotubes were prepared using methyl orange as a soft template. The microstructure and morphology of the products were characterized by scanning electron microscopy， Fourier transform infrared spectrometry， X-ray diffraction and X-ray photoelectron spectrometry， respectively. The electrochemical detection of polypyrrole nanotubes and polypyrrole nanoparticels for ascorbic acid were conducted. The result of cyclic voltammetry indicated that polypyrole nanotubes and polypyrrolenanoparticles both had electrochemical response for ascorbic acid. But the response current of polypyrrole nanotubes was higher than that of polypyrrole nanoparticles， suggesting that the polypyrrole nanotubes had better electrochemical performance. The electrochemical response of polypyrrole nanotubes for sensing ascorbic acid were further investigated by differential pulse voltammetry. The responses of this sensor were linear over the ranges of 0.5 mmol/L to 20 mmol/L and 20 mmol/L to 45 mmol/L， respectively. It indicates that the polypyrrole nanotubes can be used as promising materials in the field of electrochemical sensors.

参考文献/References:

［1］　GRIFFITHS H R， LUNEC J. Ascorbic acid in the 21st century-more than a simple antioxidant［J］. Environmental Toxicology & Pharmacology， 2001， 10（4）：173-182. ［2］　PING J， WU J， WANG Y， et al. Simultaneous determination of ascorbic acid， dopamine and uric acid using high-performance screen-printed graphene electrode ［J］. Biosensors and Bioelectronics， 2012， 34（1）：70-76. ［3］　LIU X， NA W， SU X， et al. Fluorescence turn-off-on probe based on polypyrrole/graphene quantum composites for selective and sensitive?detection?of?paracetamol and?ascorbic?acid［J］. Biosensors and Bioelectronics， 2017， 98（2）： 222-226. ［4］　QI Y， LONG H Y， MA L， et al. Enhanced selectivity?of?boron doped diamond electrodes for the?detection?of?dopamine and?ascorbic?acid?by increasing the film thickness［J］. Applied Surface Science， 2016， 390（4）： 882-889. ［5］　ABDELWAHAB A A， SHIM Y B. Simultaneous determination of ascorbic acid， dopamine， uric acid and folic acid based on activated graphene/MWCNT nanocomposite loaded Au nanoclusters［J］. Sensors & Actuators B Chemical， 2015， 221（4）： 659-665. ［6］　PENG J， LING L， ZHANG XQ， et al. A rapid， sensitive and selective colorimetric method for detection of ascorbic acid［J］. Sensors & Actuators B Chemical， 2015， 221（4）： 708-716.?［7］　YEBRA-BIURRUN M， CESPON-ROMERO R M， BERMEJO-BARRERA P. Indirectflow-injection determination of ascorbic acid by flame atomicabsorption spectrometry［J］. Microchim Acta， 1997， 126（1/2）： 53-58. ［8］　AIHUA L， JUN-ICHI A. Ferrocene-containing polyelectrolytemultilayer film-covered electrodes： electrocatalytic determination of ascorbic acid and use of inner blocking layers to improve the upper detection limit of the electrodes［J］. Analytical & Bioanalytical Chemistry， 2004， 380（1）：98-103. ［9］　ZHANG J， DENG P H， FENG L Y， et al. Electrochemical determination of ascorbic acid at γ-MnO2 modified carbon black microelectrodes［J］. Microchim Acta， 2004， 147（4）： 279-282. ［10］　JAHAN B R， ABOLFAZL K， REZA O， et al. Simultaneous voltammetric determination of ascorbic acid and dopamine at the surface of electrodes modified with self-assembled gold nanoparticle films［J］. Journal of Solid State Electrochemistry， 2010， 14（7）： 1171-1175. ［11］　MAHDIE M， SAYED M G，MOHSEN B， et al.Electrochemical determination of ascorbic acid at the surface of agraphite electrode modified with multi-walled carbonnanotubes/tetradecyltrimethyl- ammoniumbromide［J］. Journal of Applied Electr- ochemistry， 2010，40（4）： 841-847. ［12］　KEPINSKA D， BLANCHARD G J， KRYSINSKI P， et al. Pyrene-loaded polypyrrole microvessels［J］. Langmuir， 2011， 27（20）： 12720-12729. ［13］　LIU J， HE Z， XUE J， et al. A metal-catalyst free， flexible and free-standing chitosan/vacuum-stripped graphene/polypyrrole three dimensional electrode interface for high performance dopamine sensing［J］. Journal of Materials Chemistry B， 2014， 17（2）： 2478-2482. ［14］　ZHANG J， LE J， PAN R， et al. Highly sensitive electrocatalytic biosensing of hypoxanthine based on functionalization of graphene sheets with water-soluble conducting graft copolymer［J］. Biosensors and Bioelectronics， 2010， 26（2）： 371-376. ［15］　李亮， 陈旭， 艾建连. 偶氮染料掺杂聚吡咯纳米/微米结构材料的制备［J］. 武汉工程大学学报， 2013， 35（4）： 55-60. ［16］　YANG X， LI L， ZHAO Y. Ag/AgCl-decorated polypyrrole nanotubes and their sensory properties［J］. Synthetic Metals， 2010， 160（17/18）： 1822-1825.［17］　JI J， ZHANG X， LIU J， et al. Assembly of polypyrrole nanotube@MnO2 composites with an improved electrochemical capacitance［J］. Materials Science and Engineering： B， 2015， 198（1）： 51-56.

相似文献/References:

[1]朱寒冰,黄瑜,李亮.甲基橙掺杂聚吡咯纳米管的合成及其性能[J].武汉工程大学学报,2011,(07):17.
　ZHU Hanbing,HUANG Yu,LI Liang.Synthesis and performance of polypyrrole nanotubes doped with methyl orange[J].Journal of Wuhan Institute of Technology,2011,(02):17.

备注/Memo

备注/Memo:
收稿日期：2017-09-04基金项目：2016年省级大学生创新创业训练计划项目（201610490019）作者简介：陈霖进，硕士研究生。 E-mail： 412367042@qq.com*通讯作者：李　亮，博士，教授。 E-mail： msell08@163.com引文格式：陈霖进，熊惠之，喻湘华，等. 聚吡咯纳米管对抗坏血酸的电化学检测［J］. 武汉工程大学学报，2018，40（2）：132-137.
更新日期/Last Update: 2018-04-25