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[1]杨　婉,王映桂,孙　鹏,等.琼脂糖凝胶中树枝状银的生长研究[J].武汉工程大学学报,2017,39(03):248-252.[doi:10. 3969/j. issn. 1674?2869. 2017. 03. 008]
　Controlled Growth of Silver Dendrites in Agarose Gel.Controlled Growth of Silver Dendrites in Agarose Gel[J].Journal of Wuhan Institute of Technology,2017,39(03):248-252.[doi:10. 3969/j. issn. 1674?2869. 2017. 03. 008]
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琼脂糖凝胶中树枝状银的生长研究(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
39
期数:
2017年03期
页码:
248-252
栏目:
材料科学与工程
出版日期:
2017-06-24

文章信息/Info

Title:
Controlled Growth of Silver Dendrites in Agarose Gel
文章编号:
20170308
作者:
杨　婉; 王映桂; 孙　鹏; 叶均章; 吴江渝*
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
Controlled Growth of Silver Dendrites in Agarose Gel
School of Materials Science and Engineering，Wuhan Institute of Technology，Wuhan 430205，China
关键词:
琼脂糖; 银纳米粒子; 树枝状银; 复合凝胶; 可控制备
Keywords:
agarose; silver nanoparticles; silver dendrites; composite gel; controlled preparation
分类号:
O614.122
DOI:
10. 3969/j. issn. 1674?2869. 2017. 03. 008
文献标志码:
A
摘要:
以琼脂糖凝胶作为模板、还原剂和稳定剂，通过溶胶-凝胶法制备琼脂糖/纳米银复合凝胶，对所得到的银纳米粒子进行了表征. 在复合凝胶外侧使用铝箔破坏凝胶中银纳米粒子的平衡状态，实现银纳米粒子在凝胶中的聚集并生成三维树枝状结构，并对树枝状银进行了表征. 结果表明，银纳米粒子为球形，粒径在20 nm左右，分散性好. 以琼脂糖凝胶为模板生长的树枝状银形状完整，尺寸与复合凝胶的样品大小有关，可达厘米级. 树枝状银的形貌可通过改变硝酸银浓度进行调控. 树枝状银结构的形成是扩散限制凝聚的结果. 关键词：琼脂糖；银纳米粒子；树枝状银；复合凝胶；可控制备
Abstract:
garose/nanosilver composite gel was prepared by sol-gel method using agarose gel as the template， the reducing agent and the stabilizer，and the obtained silver nanoparticles were characterized. Aluminum foil was used on the outsides of composite gel to alter the equilibrium state of the silver nanoparticles in the gel and to induce the aggregation of the silver nanoparticles and the formation of a three-dimensional silver dendritic structure. These silver dendrites were also characterized by optical microscopy and scanning electronic microscopy. The results show that the synthesized silver nanoparticles are spherical and homogeneous with a size of about 20 nm. The preparation process with agarose gel as template endows the silver dendrite an intact structure. The size of the silver dendrite， which depends on the dimension of the composite gel sample， can be up to several centimeters. The morphology of silver dendrites can be regulated by adjusting the concentration of the reagent silver nitrate. The formation of silver dendrites is supposed to follow the diffusion-limited aggregation mechanism.

参考文献/References:

［1］ HUNT S T，MILINA M，ALBA-RUBIO A C，et al. Self-assembly of noble metal monolayers on transition metal carbide nanoparticle catalysts［J］. Science，2016，352（6288）：974-978. ［2］ YANG T，LIU J，DAI J，et al. Shaping particles by chemical diffusion and reaction［J］. Crystengcomm，2017，19（1）：72-79. ［3］ ZHU Y，MEI T，WANG Y，et al. Formation and morphology control of nanoparticles via solution routes in an autoclave［J］. Journal of Materials Chemistry，2011，21（31）：11457-11463. ［4］　REN W，GUO S，DONG S，et al. A simple route for the synthesis of morphology-controlled and SERS-active Ag dendrites with near-infrared absorption［J］. Journal of Physical Chemistry C，2011，115（21）：10315-10320. ［5］　张晓彤，赵春柳，周雨萌，等. 树枝状银微米材料的制备及其表面增强拉曼光谱研究［J］. 光谱学与光谱分析，2015，35（10）：2952-2957. ZHANG X T，ZHAO C L，ZHOU Y M，et al. Preparation and SERS study of silver microstructures with dendritic shape［J］. Spectroscopy and Spectral Analysis，2015，35（10）：2952-2957. ［6］　FU J，YE W，WANG C. Facile synthesis of Ag dendrites on Al foil via galvanic replacement reaction with ［Ag（NH3）2］Cl for ultrasensitive SERS detecting of biomolecules［J］. Materials Chemistry & Physics，2013，141（1）：107-113. ［7］ HUANG J，VONGEHR S，TANG S，et al. Ag dendrite-based Au/Ag bimetallic nanostructures with strongly enhanced catalytic activity［J］. Langmuir the Acs Journal of Surfaces & Colloids，2009，25（19）：11890-11896. ［8］　宋李红，易清风，唐梅香，等. 树枝状银纳米颗粒的电沉积法制备及其对葡萄糖的电催化氧化研究［J］. 分析科学学报， 2013，29（2）： 191-195. SONG L H，YI Q F，TANG M X，et al. Electrodeposition synthesis of dentrite-like Ag nanoparticles for electrocalalytic oxidation of glucose［J］. Journal of Anlytical Science，2013，29 （2）：191-195. ［9］　GAO Y，SONG J，LI S，et al. Hydrogel microphones for stealthy underwater listening ［J］. Nature Communications，2016， 7：12316-1-12316-10. ［10］ AVIZIENIS A V，MARTINOLMOS C，SILLIN H O，et al. Morphological transitions from dendrites to nanowires in the electroless deposition of silver［J］. Crystal Growth & Design，2013，13（2）：465-469. ［11］ KATSUKI A，UECHI I，FUJIWARA M，et al. High magnetic field effect on the growth of 3-dimensional silver dendrites［J］. Chemistry Letters，2002，31（12）： 1186-1187. ［12］ CUI G，QI S，WANG X，et al. Interfacial growth of controllable morphology of silver patterns on plastic substrates［J］. Journal of Physical Chemistry B，2012，116（40）：12349-12356. ［13］　SONG J，HOU J，TIAN L，et al. Growth of giant silver dendrites on layer-by-layer assembled films［J］. Polymer，2015，63：237-243. ［14］　LIU W，YANG T，LIU J，et al. Controllable synthesis of silver dendrites via an interplay of chemical diffusion and reaction［J］. Industrial & Engineering Chemistry Research，2016，55（30）：8319-8326. ［15］ ARNOTT S，FULMER A，SCOTT W E，et al. The agarose double helix and its function in agarose gel structure［J］. Journal of Molecular Biology，1974，90（2）： 269-284. ［16］ BOGOYAVLENSKIY V A，CHERNOVA N A. Diffusion-limited aggregation： a relationship between surface thermodynamics and crystal morphology［J］. Physical Review E，2000，61（2）：1629-1633. ［17］　翟爱霞，蔡雄辉，徐铖涛. 湿化学法制备微米级枝状银粉及其生长机理研究［J］. 粉末冶金材料科学与工程，2012，17（2）：196-201. ZHAI A X，CAI X H，XU C T. Preparation an formation mechanism study of micro-sized silver dendritic crystal synthesized by wet-chemical method［J］. Materials Science and Engineering of Powder Metallurgy，2012，17（2）：196-201. ［18］　BEN JACOB E，GARIK P. The formation of patterns in non-equilibrium growth［J］. Nature，1990，343（6258）：523-530.

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备注/Memo

备注/Memo:
基金项目：国家自然科学基金（51003081）；武汉工程大学第七届研究生创新基金（CX2015004）作者简介：杨　婉，硕士研究生. E-mail：1098354116@qq.com
更新日期/Last Update: 2017-06-23