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[1]黄志良*,孟 鹏,李紫谦,等.柱撑剂浓度对黑云母柱撑的影响[J].武汉工程大学学报,2015,37(08):53-57.[doi:10. 3969/j. issn. 1674-2869. 2015. 08. 011]
 ,CHEN Chang-lian,et al.Effect of different concentrations of pillared-reagent on biotite pillaring[J].Journal of Wuhan Institute of Technology,2015,37(08):53-57.[doi:10. 3969/j. issn. 1674-2869. 2015. 08. 011]
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柱撑剂浓度对黑云母柱撑的影响(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
37
期数:
2015年08期
页码:
53-57
栏目:
材料科学与工程
出版日期:
2015-08-31

文章信息/Info

Title:
Effect of different concentrations of pillared-reagent on biotite pillaring
文章编号:
1674-2869. 2015. 08. 011
作者:
黄志良*孟 鹏李紫谦陈常连张占辉
黑云母;十八烷基三甲基氯化铵;离子交换;有机柱撑
Author(s):
HUANG Zhi-liang MENG Peng LI Zi-qianCHEN Chang-lianZHANG Zan-hui
School of Material and Engineering, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
黑云母十八烷基三甲基氯化铵离子交换有机柱撑
Keywords:
biotitestearyl trimethyl ammoium chlorideion exchangeorganie pillaring
分类号:
TD985
DOI:
10. 3969/j. issn. 1674-2869. 2015. 08. 011
文献标志码:
A
摘要:
在“钡/钾离子交换”过程中,用十八烷基三甲基氯化铵柱撑黑云母,得到有机柱撑云母. 用X-射线衍射图谱和傅里叶转换红外光谱的表征手段研究了不同十八烷基三甲基氯化铵的浓度对柱撑黑云母的过程的影响. 结果表明,当十八烷基三甲基氯化铵的浓度小于0.5阳离子可交换量(CEC)时,黑云母的柱撑过程才能顺利进行;在不同十八烷基三甲基氯化铵浓度下,层间的十八烷基三甲基铵离子均以单层直链型模式(paraffin结构)分布. 柱撑液浓度逐渐增大时,十八烷基三甲基铵离子由直链倾斜状逐渐竖立起来,在0.5 CEC时,完全竖直起来.
Abstract:
The organic pillared biotite was produced by stearyl-trimethylammonium chloride(STAC) pillaring biotite in the barium/potassium ion exchange process. The effects of differe

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2015-06-16基金项目:国家自然科学基金(51374155);湖北省科技支撑计划(2014BCB034);湖北省自然科学基金(2014FB796);湖北省科技支撑计划(2015BAA105)作者简介:黄志良(1964-),男,安徽望江人,教授,博士. 研究方向:无机非金属材料的成分尧结构尧晶体化学尧制备及功能应用等方面的教学与科研.
更新日期/Last Update: 2015-09-02