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[1]余响林,张碧玉,吴杰辉,等.有机高分子絮凝剂的制备及性能[J].武汉工程大学学报,2014,(06):5-9.[doi:103969/jissn16742869201406002]
　YU Xiang lin,ZHANG Bi yu,WU Jie hui,et al.Preparation and properties of organic polymer flocculant[J].Journal of Wuhan Institute of Technology,2014,(06):5-9.[doi:103969/jissn16742869201406002]
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有机高分子絮凝剂的制备及性能(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2014年06期
页码:
5-9
栏目:
化学与化学工程
出版日期:
2014-06-30

文章信息/Info

Title:
Preparation and properties of organic polymer flocculant
文章编号:
16742869(2014)06000505
作者:
余响林; 张碧玉; 吴杰辉; 胡甜甜; 秦天
武汉工程大学化工与制药学院, 湖北 武汉 430074
Author(s):
YU Xianglin; ZHANG Biyu; WU Jiehui; HU Tiantian; QIN Tian
School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Wuhan 430074,China
关键词:
有机絮凝剂; 含油废水; 水溶液聚合; 反相乳液聚合
Keywords:
organic flocculant; oily wastewater; aqueous solution polymerization; inverse emulsion polymerization
分类号:
O 631.5
DOI:
103969/jissn16742869201406002
文献标志码:
A
摘要:
为解决常用絮凝剂存在低效高耗、二次污染等问题，提出使用有机高分子絮凝剂处理含油废水．通过有机单体丙烯酰胺、丙烯酸、2丙烯酰胺基2甲基丙烷磺酸的水溶液聚合和反相乳液聚合，经红外光谱的结构验证和对含油废水的实际处理，确定了用反相乳液聚合法合成的絮凝剂具有较好的絮凝效果．考察了pH值、絮凝剂的投加量、水温等因素对絮凝效果的影响．结果表明，在常温下絮凝剂投加量为230 mg/L，pH值为6时可以取得最佳的絮凝效果，其对废水中油类的去除率可达90.1%．
Abstract:
To solve the problems existed in the common flocculant during oily wastewater treatment,such as low efficient ,high cost and secondary pollution,a kind of organic polymer flocculant was adopted to deal with the oily wastewater.The flocculant were prepared by acrylamide,acrylic acid,2acrylamido2 methyl propane sulfonic acid through aqueous solution polymerization and inverse emulsion polymerization.The flocculant prepared by inverse emulsion polymerization has better flocculation effect according to the structure verification by infrared spectra and the actual treatment effect analysis of oily wastewater.The effects of pH,the amount of flocculant and the temperature of water on the flocculants efficiency were investigated.The results show that the best flocculating rate reaches to 90.1% under room temperature when the flocculant dosage is 230 mg/L and pH value is 6.

参考文献/References:

［1］张亚文,胡东升,彭炳乾.水处理絮凝剂研究进展［J］.石化技术与应用,2009,27(5):470477.ZHANG Y W,HU D S,PENG B Q.Progress in research of flocculantes for wastewater treatment［J］.Petrochemical Technology & Application,2009,27(5):470477.(in Chinese)［2］壮亚峰,曹桂萍,张潇潇.氢氧化镁壳聚糖复合絮凝剂对印染废水的脱色研究［J］.环境科学与管理,2008,33(1):7073.ZHUANG Y F,CAO G P,ZHANG X X.Study on the decolorization of dyeing wastewater using magnesium hydroxidechitosan complex flocculant［J］.Environmental Science and Management,2008,33(1):7073.(in Chinese)［3］黎载波,王国庆,邹龙生.有机高分子絮凝剂在印染废水处理中的应用［J］.工业水处理,2003,23(4):1417. LI Z B,WANG G Q,ZOU L S.Progress of organic polymer flocculant applied to dyeing waste water treatment［J］.Industrial Water Treatment,2003,23(4):1417.(in Chinses)［4］周东美,郝秀珍,薛艳,等.污染土壤的修复技术研究进展［J］.生态环境,2004,13(2):234242.ZHOU D M,HAO X Z,XUE Y,et al.Advances in remediation technologies of contaminated soils［J］.Ecology and Environment,2004,13(2):234242.(in Chinses)［5］马红霞,李耀仓,肖铮.环保型复合絮凝剂的制备与应用［J］.安徽农业科学,2012,40(24):1215112153.MA H X,LI Y C,XIAO Z.The preparation and application of environmentfriendly compound flocculant［J］.Journal of Anhui Agri Sci,2012,40(24):1215112153.(in Chinese)［6］杨晓霞,华涛,周启星,等.水处理复合絮凝剂的研究及应用进展［J］.水处理技术,2007,33(12):1118.YANG X X,HUA T,ZHOU Q X,et al.Progress in researches and application in synthetical flocculants for waste water treatment［J］.Technology of Water Treatment,2007,33(12):1118.(in Chinese)［7］关晓辉,刘海宁,马致义,等.新型高效絮凝剂生物聚合硫酸铁的制备及性能研究［J］.环境污染治理技术与设备,2005,5(1):6971.GUAN X H,LIU H N,MA Z Y,et al.Preparation of biological polyferric sulfate as a new high efficiency flocculant and its properties［J］.Techniques and Equipment for Environmental Pollution Control,2005,5(1):6971.(in Chinese)［8］夏德强,王萍,付君善,等.新型环保絮凝剂APAC的制备及性能表征［J］.中国给水排水,2008,24(15):8285. XIA D Q,WANG P,FU J S,et al.Preparation and characterization of a novel environmentfriendly flocculant APAC［J］.China Water&Wastewater,2008,24(15):8285.(in Chinese)［9］杨爱丽,蒋文举.淀粉接枝丙烯酰胺共聚物与聚氯化铝复合絮凝剂的合成［J］.高分子材料科学与工程,2008,24(7):5255.YANG A L,JIANG W J.Synthesis of the composite flocculant of starchgraftacrylamide with polyaluminum chloride［J］.Polymer Materials Science and Engineering,2008,24(7):5255.(in Chinese)［10］夏德强,王萍,付君善,等.凹凸棒聚氯化铝复合絮凝剂的制备及应用［J］.石化技术与应用,2009,27(1):2023.XIA D Q,WANG P,FU J S,et al.Preparation and application of composite flocculent of attapulgite poly(aluminum chloride)［J］.Petrochemical Technology & Application,2009,27(1):2023.(in Chinese)［11］CHEN J P,ZHANG L Y,WANG W H,et al.Screening of flocculantproducing microorganisms and flocculating activity［J］.Journal of Environmental Sciences,2004,16(6):894897.［12］RANI P,SEN G,MISHRA S,et al.Microwave assisted synthesis of polyacrylamide grafted gum ghatti and its application as flocculant［J］.Carbohydrate Polymers,2012,89(1):275281.

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备注/Memo

备注/Memo:
收稿日期：20140416基金项目：国家自然科学基金(51203127)；湖北省教育厅优秀中青年项目(20121509)；武汉市科技局青年科技晨光计划项目(201050231049)；绿色化工过程省部共建教育部重点实验室开放基金项目(GCP201003)；武汉工程大学科学研究基金(10092012)作者简介：余响林（1980），女，湖北武汉人，副教授，博士．研究方向：功能高分子材料．
更新日期/Last Update: 2014-07-29