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[1]郭志荣,奚强*,陈建,等.2羟异丙基丙烯酸酯的合成工艺[J].武汉工程大学学报,2011,(04):23-25,29.[doi:10.3969/j.issn.16742869.2011.04.006]
　GUO Zhirong,XI Qiang,CHEN Jian,et al.Research on synthesis process of 2hydroxyisopropyl acrylate[J].Journal of Wuhan Institute of Technology,2011,(04):23-25,29.[doi:10.3969/j.issn.16742869.2011.04.006]
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2羟异丙基丙烯酸酯的合成工艺(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2011年04期
页码:
23-25,29
栏目:
化学与化学工程
出版日期:
2011-04-30

文章信息/Info

Title:
Research on synthesis process of 2hydroxyisopropyl acrylate
文章编号:
16742869(2011)04002303
作者:
郭志荣1; 奚强1*; 陈建2; 张晓1; 王庆利1
1.武汉工程大学化工与制药学院,湖北武汉430074；2.武汉理工大学化学工程学院,湖北武汉430070
Author(s):
GUO Zhirong1;  XI Qiang1;  CHEN Jian2;  ZHANG Xiao1;  WANG Qingli1
1.School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430074, China
2.Chemical Engineering Institute, Wuhan Institute of Technology, Wuhan 430070, China
关键词:
环氧丙烷; 羟异丙基丙烯酸酯; 合成工艺
Keywords:
propylene;  2hydroxyisopropyl acrylate;  synthesis process
分类号:
TQ225.24+1
DOI:
10.3969/j.issn.16742869.2011.04.006
文献标志码:
A
摘要:
以丙烯酸和环氧丙烷为原料,经开环的方法得到2羟异丙基丙烯酸酯.并考察了各因素对反应收率的影响,确定了最适反应条件：催化剂的量为原料总质量的1.5%,反应时间12 h,投料质量比11.6.最终产品的收率可达82.7%,纯度97.00%以上,并用核磁（1H NMR）和红外对产品的结构进行了表征.
Abstract:
2hydroxyisopropyl acrylate was synthesized from acrylic acid and propylen by ring opening reaction. The product was obtained in a yield of ca 82.7% with a purity over 97% under best reaction condition, which was at 60 ℃ for 12 h using 1.5% catalyst, and the feed ratio of original material was 11.6. Chemical structure of product was characterized by 1H NMR and Infrared spectrum.

参考文献/References:

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［2］张文郁,董庆年,赵宁,等.环氧丙烷和甲醇在MgO上合成1甲氧基2丙醇反应机理［J］.物理化学学报,2005,21(6):653657.
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［4］陈尚东,李刚,何玲玲.ZrO2/SO4超强酸催化环氧丙烷醇解反应研究［J］.当代化工,2006,6(35)：365367.
［5］Ingleson M J, Barrio J P, Bacsa J,et al. Generation of a solid Bronsted acid site in a chiral framework［J］.The Royal Society of Chemistry,2008:12871289.
［6］Deng Kuilin, Tian Hua, Zhang Pengfei, et al. pHTemperature Responsive Poly(HPACOAMHS) Hydrogel as A Potential DrugRelease Carrier［J］. Journal of Applied Polymer Science,2009,114:176184.
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备注/Memo

备注/Memo:
收稿日期：20110113作者简介：郭志荣(1986)，女，湖北仙桃人，硕士研究生.研究方向：有机合成.指导老师：奚强，副教授，博士，硕士研究生导师.研究方向：有机合成.
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