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[1]白 娟,周兴平*,解孝林*.微晶纤维素对两步拉伸挤出的PBAT/TPS共混材料的结构与性能的影响[J].武汉工程大学学报,2022,44(05):522-527.[doi:10.19843/j.cnki.CN42-1779/TQ.202206020]
 BAI Juan,ZHOU Xingping*,XIE Xiaolin*.Effect of Microcrystalline Cellulose on Structure and Properties of?PBAT/TPS Blends Based on Two-Step Elongational Extrusion[J].Journal of Wuhan Institute of Technology,2022,44(05):522-527.[doi:10.19843/j.cnki.CN42-1779/TQ.202206020]
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微晶纤维素对两步拉伸挤出的PBAT/TPS共混材料的结构与性能的影响(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
44
期数:
2022年05期
页码:
522-527
栏目:
50周年校庆特刊
出版日期:
2022-10-31

文章信息/Info

Title:
Effect of Microcrystalline Cellulose on Structure and Properties of?PBAT/TPS Blends Based on Two-Step Elongational Extrusion

文章编号:
1674 - 2869(2022)05 - 0522 - 06
作者:
白 娟13周兴平*12解孝林*12
1. 华中科技大学化学与化工学院,湖北 武汉 430074;
2. 材料成形与模具技术国家重点实验室(华中科技大学),湖北 武汉 430074;
3. 武汉华丽环保科技有限公司,湖北 武汉 430200

Author(s):
BAI Juan13ZHOU Xingping*12XIE Xiaolin*12

1. School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China;
2. State Key Laboratory of Material Processing and Die & Mould Technology(Huazhong University of Science and Technology),Wuhan 430074,China;3. Wuhan Huali Environmental Technology Co.,Ltd,Wuhan 430200,China

关键词:
聚己二酸/对苯二甲酸丁二酯热塑性淀粉微晶纤维素拉伸挤出生物降解高分子
Keywords:
poly(butylene adipate-co-terephthalate)thermoplastic starchmicrocrystalline celluloseelongational extrusionbiodegradable polymer
分类号:
TQ 323.4
DOI:
10.19843/j.cnki.CN42-1779/TQ.202206020
文献标志码:
A
摘要:
采用偏心转子挤出机两步挤出法,制备了聚己二酸/对苯二甲酸丁二酯(PBAT)/热塑性淀粉(TPS)/微晶纤维素(MCC)复合材料,研究了MCC对复合材料的形貌、结晶结构、力学和热性能的影响。并通过组分和加工工艺优化,制备了PBAT/TPS/MCC复合薄膜,研究了薄膜的力学性能和对水汽的阻隔能力。结果表明,经过两步拉伸挤出加工后,MCC在共混物中分散均匀,提升了增容PBAT/TPS共混物的结晶度和热稳定性。同时,PBAT/TPS/MCC复合材料保持了双连续相结构,具有高的弹性模量。这为制备高性能、低成本的生物降解材料提供了新思路。
Abstract:
The poly(butylene adipate-co-terephthalate)/thermoplastic starch/microcrystalline cellulose(PBAT/TPS/MCC) composites were manufactured by double-axis eccentric rotor extruder based on two-step elongational extrusion. The effects of MCC on the morphology,crystalline structure,mechanical performance and thermal property of composites were systematically studied. Furthermore,the PBAT/TPS/MCC film was manufactured by optimizing composition and processing technology,and the mechanical and water vapor barrier performances of film were also investigated. The results indicated that the MCC is uniformly dispersed in the blend after the two-step elongational extrusion process,which enhances the crystallinity and thermal stability of the compatibilized PBAT/TPS blends. Meanwhile,the PBAT/TPS/MCC composites maintaine a bi-continuous phase structure and have a high elastic modulus. This study provides a new idea for preparing the biodegradable materials with high performance and low cost.

参考文献/References:

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相似文献/References:

备注/Memo

备注/Memo:
收稿日期:2022-06-13
基金项目:国家重点研发计划项目(2016YFB0302400)
作者简介:白 娟,博士,高级工程师。E-mail:baijuan@psm.com.cn
*通讯作者:周兴平,博士,教授。E-mail:xpzhou@hust.edu.cn
解孝林,博士,教授。E-mail:xlxie@hust.edu.cn
引文格式:白娟,周兴平,解孝林. 微晶纤维素对两步拉伸挤出的PBAT/TPS共混材料的结构与性能的影响[J]. 武汉工程大学学报,2022,44(5):522-527,533.

更新日期/Last Update: 2022-11-01