|本期目录/Table of Contents|

[1]梅　杰１,田回香１,夏语嫣,等.丙二胺铜配合物的合成、晶体结构和热稳定性[J].武汉工程大学学报,2019,(01):19-24.[doi:10. 3969/j. issn. 1674?2869. 2019. 01. 003]
　MEI Jie,TIAN Huixiang,XIA Yuyan,et al.Synthesis, Crystal Structure and Thermal Stability of Copper Complex of 1,3-Propane Diamine[J].Journal of Wuhan Institute of Technology,2019,(01):19-24.[doi:10. 3969/j. issn. 1674?2869. 2019. 01. 003]
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丙二胺铜配合物的合成、晶体结构和热稳定性(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2019年01期
页码:
19-24
栏目:
化学与化学工程
出版日期:
2019-03-23

文章信息/Info

Title:
Synthesis, Crystal Structure and Thermal Stability of Copper Complex of 1,3-Propane Diamine
文章编号:
20190103
作者:
梅　杰１; 田回香１; 夏语嫣;  巫烨文１; 周　红*2
1. 武汉工程大学国际学院，湖北 武汉 430074;2. 武汉工程大学化学与环境工程学院，湖北 武汉 430205
Author(s):
MEI Jie1;  TIAN Huixiang1; XIA Yuyan1;  WU Yewen1;  ZHOU Hong*2
1. School of International Education, Wuhan Institute of Technology, Wuhan 430074, China；2. School of Chemical and Environmental Engineering, Wuhan Institute of Technology,Wuhan 430205, China
关键词:
1; 3-丙二胺; 晶体结构; 铜聚合物; 含氯氢键
Keywords:
1; 3-propane diamine; crystal structure; copper(II) polymer; chlorinum-containing-hydrogen bond
分类号:
O611.4
DOI:
10. 3969/j. issn. 1674?2869. 2019. 01. 003
文献标志码:
A
摘要:
CuCl2与1,3-丙二胺（pn）在甲醇中反应获得了一个意想不到的络合物，其最大晶体尺寸约为7 mm×3 mm× 5 mm。通过红外光谱，元素分析和X射线衍射表征该配合物，结果表明，该复合体具有三维网络结构。三维网状结构是由于配位离子[CuCl(pn)2]+与Cl-之间的氢键和静电相互作用而形成的，其中CH3OH也参与氢键相互作用。另外，使用热重分析和差示扫描量热技术研究了该络合物的热稳定性。结果表明，相互作用的热稳定序列（从强到弱）是静电作用，配位作用和氢键作用。协同相互作用有助于形成更大尺寸的配合物晶体。
Abstract:
An unexpected complex with the maximum crystal size of about 7 mm×3 mm× 5 mm was prepared by a reaction of CuCl2 with 1,3-propane diamine(pn) in methanol. The characterization results with infrared spectroscopy, elemental analysis and X-ray diffraction show that the complex exhibits three dimensional network structure, which is contributed to the hydrogen bonding and electrostatic interactions between coordination ion [CuCl(pn)2]+ and its counter anion Cl-, where CH3OH also participates the hydrogen bonding interactions. In addition, thermogravimetric analysis and differential scanning calorimetry techniques show that the thermal stability of synergistic interactions increases in the order of electrostatic, coordination and hydrogen bond. The synergistic interactions are in favor of the formation of bigger size crystals of the complex.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：2018-04-03基金项目：国家自然科学基金(21171135)；武汉工程大学第十届本科校长基金（2015073）作者简介：梅　杰. E-mail：2662915122@qq.com*通讯作者：周　红，博士，教授. E-mail：hzhouh@126.com引文格式：梅杰，田回香，夏语嫣，等. 丙二胺铜配合物的合成、晶体结构和热稳定性［J］. 武汉工程大学学报，2019，41（1）：19-24.
更新日期/Last Update: 2019-02-18