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[1]陈金芳,万革枝,陈启明,等.湖北某厂以清洁生产为目标的污水治理方案[J].武汉工程大学学报,2014,(08):1-9.[doi:103969/jissn16742869201408001]
　CHEN Jin fang,WAN Ge zhi,CHEN Qi ming,et al.Wastewater treatment for cleaner production of Hubei factory[J].Journal of Wuhan Institute of Technology,2014,(08):1-9.[doi:103969/jissn16742869201408001]
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2014年08期
页码:
1-9
栏目:
资源与土木工程
出版日期:
2014-08-31

文章信息/Info

Title:
Wastewater treatment for cleaner production of Hubei factory
文章编号:
16742869(2014)08000109
作者:
陈金芳1; 万革枝2; 陈启明2; 王亚2; 邹菁3; 汤亚飞4; 张良均5
1．武汉工程大学绿色化工过程教育部重点实验室,湖北 武汉 430074；2．武汉工程大学化工与制药学院，湖北 武汉 430074；3．武汉工程大学分析与测试中心，湖北 武汉 430074；4．武汉工程大学化学与环境工程学院，湖北 武汉 430074；5．湖北省化工清洁生产研究中心，湖北 武汉 430074
Author(s):
CHEN Jinfang1;  WAN Gezhi2;  CHEN Qiming2;  WANG Ya2;  ZOU Jing3;  TANG Yafei4; ZHANG Liangjun5
1. Key laboratory for Green Chemical Process (Wuhan Institute of Technology)，Ministry of Education, Wuhan 430074, China;2. School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology，Wuhan 430074, China;3. Center of Analysis and Test of Wuhan Institute of Technology, Wuhan 430074, China;4. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology，Wuhan 430074, China;5. Research Center of Chemical Cleaner Production of Hubei, Wuhan 430074, China
关键词:
化工废水; 生化过程; 耗氧解毒; 催化燃烧; 气提
Keywords:
chemical wastewater;  biochemical process;  oxygen consumption detoxification;  catalytic combustion;  stripping
分类号:
X703
DOI:
103969/jissn16742869201408001
文献标志码:
A
摘要:
在化工制药生产过程中，产生一类以分子量小、挥发性较强，对生化过程有害的污水,使上流式厌氧污泥床反应器(UASB)系统难以正常工作.为解决这类化工污水的生化消解问题，以湖北某厂生产吡哆醇盐酸盐产生的污水治理为例，应用“鱼刺图”的方法分析，找到了该企业生化系统不能开车正常的主要原因是三乙胺和正丁醛杀灭或抑制了菌群的生长.提出了——对三乙胺和正丁醛等进行氧化解毒是确保该UASB系统正常开车的关键.在协同使用气提回收三乙胺和正丁醛等，曝气脱毒，催化燃烧曝气后的稀相有害物质的基础上，提出了该企业实践清洁生产的实施方案.
Abstract:
The wastewater with small molecules, strong volatility is produced in the chemical pharmaceutical production process, which is harmful to the growth of bacteria to make the up flow anaerobic sludge blanket system not run normally. Taking the wastewater from a factory in Hubei as a case, it was found by fishbone diagram that the growth of bacteria colonies was inhibited or induced by butyraldehyde and triethylamine, so the oxygen consumption detoxification for butyraldehyde and triethylamine is the key to the upflow anaerobic sludge blanket system running normally. An implementation plan for cleaner production to the factory is presented on the basis of tripping for recycling butyraldehyde and triethylamine, aeration and catalytic combustion for harmful materials.

参考文献/References:

［1］环境保护部,国家质量监督检验检疫总局.GB/T219042008化学合成类制药工业水污染物排放标准［S］. 北京:中国标准出版社，2008.Ministry of Environmental Protection of the People’s Republic of China,General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. GB/T210942008 Discharge standards of water pollutants for pharmaceutical industry: Chemical synthesis products category［S］. Beijing:Standards Press of China, 2008.(in Chinese) ［2］李亚峰，高颖.制药废水处理技术研究进展［J］.水处理技术，2014（5）:14.LI Yafeng, GAO Ying. Research progress in the treatment technologies of pharmaceutical wastewater［J］. Technology of Water Treatment，2014（5）：14.（in Chinese）［3］芦昱，张艳，陆朝阳.化工废水深度处理技术研究进展［J］. 精细与专用化学品,2012（9）：3134.LU Yu, ZHANG Yan, LU Zhaoyan. Research progress on advanced treatment technology of chemical waste water［J］. Fine and Specialty Chemical, 2012(9):3134.（in Chinese）［4］建峥嵘.合成制药废水处理技术研究与进展［J］.贵州化工,2012（4）：2326，32.JIAN Zhengrong .Research and progress of the chemical synthesisbased pharmaceutical wastewater treatment technology［J］. Guizhou Chemical Industry, 2012(4):2326，32.（in Chinese）［5］徐勇智，范卫东，党登峰，等.维生素B6的合成研究进展［J］.广州化工, 2012, 40(6)：5051，62.XU Yongzhi, FAN Weidong, DANG Dengfeng, et al. Process in synthesis of vitamin B6［J］.Guangzhou Chemical Industry, 2012, 40(6):5051，62.（in Chinese）［6］英智威，段梅莉，冀亚飞.盐酸吡哆醇的合成［J］.中国医药工业杂志, 2009,40(2):8182，96.YING Zhiwei, DUAN Meili, JI YaFei. Synthesis of pyridoxine hydrochloride［J］. Chinese Journal of Pharmaceuticals，2009, 40(2):8182，96.（in Chinese）［7］陈天豪，李仁宝，杨威.维生素B6的合成工艺改进［J］. 中国医药工业杂志,2004,35(1):12.CHEN Tianhao, LI Renbao, YANG Wei. Improved synthesis of vitamin B6［J］. Chinese Journal of Pharmaceuticals, 2004, 35(1):12.（in Chinese）［8］许立铭,刘金霞,唐和清,等. 醛类化合物对硫酸盐还原菌的抑灭能力［J］. 油田化学, 1993（3）:260263. XU Liming, LIU Jinxia, Tang Heqing,et al. Bactericidal power of aldehydic compounds for sulfatereducing bacteria［J］.Oil field Chemistry, 1993（3）:260263.（in Chinese）［9］WANG, LU K L, CHEN X Y. Removal of triethylamine from synthetic wastewater by acclimated mixed bacteria cultures ［J］. International Biodeterioration ＆ Biodegradation, 2007, 59( 3) : 202205.［10］沈敏雅，胡江，蔡舒，等. 三乙胺降解菌SYA1 的分离、降解性能与动力学［J］.环境工程学报，2014（3）:12431249.SHEN Minya, HU Jiang, CAI Shu, et al.Isolation and degradation characteristics of a triethylamine degrading strain SYA1 and its kinetics［J］. Chinese Journal of Environmental Engineering, 2014（3）:12431249.（in Chinese）［11］杨雅茹，胡红文，白林.温度对UASB工艺的影响研究［J］.家畜生态学报，2014（4）:8389.YANG Yaru, HU Hongwen，BAI Li.Effect of temperature on uasb: a review［J］.Acta Ecologiae　Animalis　Domastici, 2014（4）:8389.（in Chinese）［12］陆正禹,王勇军，任立人.UASB处理链霉素废水颗粒污泥培养技术探索［J］.中国沼气, 1997, 15 ( 3) : 11. LU Zhengyu,WANG Yongjun,REN Liren . Exploretion on cultivating granular sludge in uasb reactor treating streptomycin wastewater［J］.China Biogas, 1997, 15 ( 3) : 11.（in Chinese）［13］刘妙丽. 水中苯和甲苯挥发速率的研究［J］. 四川师范大学学报：自然科学版, 2007（5）: 660662.LIU Miaoli. Study on the vaporization velocity of benzene and toluene in water［J］. Journal of Sichuan Normal University ：Natural Science, 2007（5）:660662.（in Chinese）［14］万斌,李振玉,刘正. 甲苯对厌氧反应过程的影响研究［J］. 化学与生物工程,2012（7）:7274.WAN Bin, LI Zhenyu, LIU Zheng. Research on effect of toluene on anaerobic reaction process［J］. Chemistry & Bioengineering, 2012（7）:7274.（in Chinese）［15］中华人民共和国第十一届全国人民代表大会常务委员会. 中华人民共和国清洁生产促进法［Z］.20120229.Cleaner Production Promotion Law of the People’s Republic of China. The Standing Committee of the National People’s Congress (NPC) of the People’s Republic of China［Z］.February 29, 2012.［16］中华人民共和国第十一届全国人民代表大会常务委员会. 中华人民共和国循环经济促进法［Z］.20080829.Circular economy law of the People’s Republic of China. The Standing Committee of the National People’s Congress (NPC) of the People’s Republic of China［Z］.August 29, 2008.［17］谢钦铭.三乙胺对水生生物毒性的研究［J］.江西大学学报： 自然科学版, 1992(1):8894.XIE Qinming. Study of toxicity of tricthylamine to aquatic organism［J］. Journal of Jiangxi University：Natural Science, 1992(1): 8894.（in Chinese）［18］李慧明,朱红伟. 对目前中国循环经济理论研究的几点思考［J］. 中国地质大学学报：社会科学版,2006（3）:1116.LI Huiming, ZHU Hongwei. Reflections on the current research situation of china’s circular economy［J］. Journal of China University of Geosciences：Social Sciences Edition ,2006（3）:1116.（in Chinese）［19］范卫东，章根宝，党登峰. 维生素B6 合成中的DielsAlder 反应及重排机理研究［J］. 广东化工,2012(12):7374.FAN Weidong, ZHANG Genbao, DANG Dengfeng. Study on dielsalder reaction and arrangement mechanism in synthesis of vitamin B6［J］. Guangdong Chemical Industry, 2012(12):7374.（in Chinese）［20］周后元，方资婷，叶鼎彝，等. 维生素B6噁唑法合成新工艺［J］. 中国医药工业杂志，1994, 25(9):385389.ZHOU Houyuan, FANG Ziting, YE Dingyi, et al. A novel synthetic technique of vitamin B6［J］. Chinese Journal of Pharmaceuticals, 1994, 25(9):385389.（in Chinese）［21］张君，刘宏娟，刘德华. 不同类型载气对乙醇气提发酵的影响［J］. 过程工程学报, 2005 (3) :349352.ZHANG Jun, LIU Hongjuan, LIU Dehua. Effect of different types of gas in gas stripping ethanol fermentation (GSEF)［J］.The Chinese Journal of Process Engineering, 2005(3):349352.（in Chinese）［22］李宇庆，马楫，钱国恩.制药废水处理技术进展［J］. 工业水处理,2009(12):57.LI Yuqing，MA Ji，QIAN Guoen. Progress in the treatment technology of pharmaceutical wastewater［J］. Industrial Water Treatment, 2009(12):57.（in Chinese）

相似文献/References:

备注/Memo

备注/Memo:
收稿日期：20140808作者简介：陈金芳（1957），男，湖北黄冈人，教授，硕士，硕士研究生导师．研究方向：精细化工、化工废物资源化．
更新日期/Last Update: 2014-09-16