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[1]王宁,胡萍,*,等.以菜籽油为基础油的绿色润滑剂制备[J].武汉工程大学学报,2012,(3):15-17.
　WANG Ning,HU Ping,YUAN Ji\|yong,et al.Preparation of green lubricants used rapeseed oil as base oil[J].Journal of Wuhan Institute of Technology,2012,(3):15-17.
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2012年3期
页码:
15-17
栏目:
化学与化学工程
出版日期:
2012-03-31

文章信息/Info

Title:
Preparation of green lubricants used rapeseed oil as base oil
文章编号:
16742869(2012)03001503
作者:
王宁1; 胡萍1;  2*; 袁继勇2; 黄樟华2; 熊先江1; 潘濛1;  罗琴琴1
1. 武汉理工大学化学工程学院，湖北 武汉 430070；
2. 浙江宝晟铁路新材料科技有限公司，浙江 嵊州 312400
Author(s):
WANG Ning1; HU Ping1; 2; YUAN Ji\|yong2; HUANG Zhang\|hua2; XIONG Xian\|jiang1; PAN Meng1; LUO Qing\|qing1
1. Department of Chemical Engineering, Wuhan University of Technology, Wuhan 430070, China；
2. Zhejiang Baosheng Railway Materials Co.Ltd, Shengzhou 312400, China
关键词:
菜籽油; 环氧化; 酯交换; 摩擦性能; 降解性能
Keywords:
rapeseed oil; epoxidation; transesterification; friction properties; degradation
分类号:
TQ645.1;TQ646
DOI:
-
文献标志码:
AAdoi:103969/jissn16742869201203004
摘要:
以菜籽油为原料，通过环氧化、酯交换反应对菜籽油进行改性，制备一种绿色润滑剂基础油环氧脂肪酸甲酯；并对菜籽油和改性菜籽油的结构进行红外表征；同时测定其抗氧化、摩擦、微生物降解和其他理化性能.结果表明：最终产品环氧脂肪酸甲酯的碘值为3.6；最大无卡咬负荷PB值达到333 N；运动粘度为9.6 mm2/s，且具有较强的生物降解能力.红外光谱证明了改性后的菜籽油中存在环氧键和甲酯基团.
Abstract:
 Rapeseed oil named epoxy fatty acid methyl ester was modified by epoxidation and ester exchange reaction.Then the structure of rapeseed oil and modified rapeseed oil was charactered by infrared Spectroscopy.And oxidative stability,friction,biodegradability and other physical and chemical properties were determined. The results show that the iodine value of epoxy fatty acid methyl ester of the final product obtained is 3.6，the maximum no seizure load PB  is 333 N，kinematic viscosity of the product is 9.6 mm2/s,and epoxy fatty acid methyl ester has better biodegrad ability.Infrared spectroscopy proves that epoxy bond and methyl ester group are found in the modified rapeseed oil.

参考文献/References:

［1］陈波水,方建华,李芬芳. 环境友好润滑剂［M］. 北京：中国石化出版社,2006.
［2］叶斌,陶德华. 环境友好润滑剂的特点及发展［J］. 润滑与密封,2002(5):73-76.
［3］王怀文,刘维明. 植物油作为环境友好润滑剂的研究概况［J］. 润滑与密封,2004（5）:127-130.
［4］张强,李文林,郑畅,等. 菜籽油环氧化新工艺制备润滑油基础油的研究［J］. 可再生能源，2009（4）:20-23.
［5］李美华,袁存光. 植物油脂酯交换法合成脂肪酸甲酯［D］.青岛：中国石油大学化学工程学院,2007.
［6］郭学阳. 环氧菜籽油生产技术［J］. 安徽化工,1990（4）:20-22.
［7］韩恒文,刘学傧. 植物油环境友好润滑油的改性研究进展［J］. 润滑油,2008（12）:6-12.
［8］吕亮. 菜油酯交换新进展［J］. 中国油脂,2000，25（4）:20-21.
［9］Holser R A . Transesterificantion of epoxidized soybean oil to prepare epoxy methyl esters ［J］. Industrial Crops and Products，2008,27:130-132.
［10］Adhvaryu A, Erhan S Z. Epoxidized Soybean Oil as a Potential Source of High-temperature Lubricants［J］. Industrial Crops and Products，2002,15:247-254.
［11］卢艳杰. 油脂检测技术［M］. 北京：化学工业出版社,2004.
［12］王昆. 润滑油生物降解性快速测定方法的研究［D］. 重庆:后勤工程学院,2004.
［13］胡志梦,党鸿辛. 植物油脂肪酸的摩擦特性［J］. 润滑油,2000,15(4):38-40.
［14］Havet L,Blouet J,Valloire F R,et al. Tribological characteristics of some environmentally friendly lubricants［J］.Chemical engineering, 2001, 248:140-146.
［15］Thompson B A W，Goldsworthy P M,Riddle M J,et al. Contamination effects by a conventional and a biodegradable lubricant oil on infaunal recruitment to Antarctic［J］. Chemical Communication, 2007,340:213-226.

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