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[1]吴点,王存文*,王为国,等.高浓度含酚废水资源化利用[J].武汉工程大学学报,2012,(3):5-10.
　WU Dian,WANG Cun\|wen,WANG Wei\|guo,et al.Utilization of high concentration phenol\|containing wastewater[J].Journal of Wuhan Institute of Technology,2012,(3):5-10.
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2012年3期
页码:
5-10
栏目:
化学与化学工程
出版日期:
2012-03-31

文章信息/Info

Title:
Utilization of high concentration phenol\|containing wastewater
文章编号:
16742869(2012)03000506
作者:
吴点; 王存文*; 王为国; 吕仁亮; 覃远航
武汉工程大学绿色化工过程省部共建教育部重点实验室，湖北 武汉 430074
Author(s):
WU Dian;  WANG Cun\|wen; WANG Wei\|guo; LV Ren\|liang; QIN Yuan\|hang
Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
含酚废水; 酚醛缩合; 尿醛缩合; 回收;  经济评价
Keywords:
phenol\|containing wastewater;  phenol\|formaldehyde condensation;  urea\|formaldehyde condensation;  recovery;  economic evaluation
分类号:
TQ09
DOI:
-
文献标志码:
AAdoi:103969/jissn16742869201203002
摘要:
采用两次酚醛缩合-尿醛缩合的方法处理含酚废水，实验室小试考察了酚醛一次缩合的甲醛用量、二次缩合的反应温度、时间、甲醛用量及催化剂含量对除酚效果的影响；尿素投料批数、反应时间、反应温度和尿素/甲醛摩尔比对除醛效果的影响.一次缩合后酚含量可降至8 000 mg/L以下，酚回收率为88.6%.二次缩合后废水酚含量可降至50 mg/L以下,两次缩合后酚总回收率达99.0%,缩合回收的酚醛树脂可作为生产原料回用.用与甲醛等摩尔比的尿素处理两次缩合后的废水，甲醛含量可降至300 mg/L以下，可直接生化处理.中试验证试验表明其结果优于小试，说明小试实验数据可靠.中试试验初步经济衡算表明，每吨废水回收约50 kg酚醛树脂，扣除生产原料和水电等成本费用可获毛利260元左右，具有良好的经济效益.
Abstract:
 The phenols in phenolic wastewater are treated by twice phenol\|formaldehyde and urea\|formaldehyde condensation process. We investigated the effect of factors such as formaldehyde consumption in the first phenol\|formaldehyde condensation, temperature and time of reaction, consumption of formaldehyde and catalyst in the second condensation on phenol removal, and then studied the effect of factors such as urea feeding times, temperature and time of reaction and urea molar ratio in urea\|formaldehyde condensation on formaldehyde removal in laboratory. The phenol content is less than 8 000 mg/L and the phenol recovery is 88.6% after the first condensation while it is less than 50 mg/L after the second condensation, the twice condensation phenol recovery reaches to 99%. Condensation of phenol\|formaldehyde resin can be used as a raw material. Formaldehyde content of the wastewater after condensation treated with urea is less than 300 mg/L, so that the wastewater can be treated directly by biochemical method. Pilot\|scale validation results are better than the small scale, indicating that small scale experimental data is reliable. Pilot\|scale preliminary economic accounting shows that every ton of wastewater can be recycled about 50 kg phenolic resin, the gross profit may be around 260 Yuan deducting the cost of raw materials and utilities. The method of twice phenol\|formaldehyde and urea\|formaldehyde condensation has a good economic benefit.

参考文献/References:

［1］王韬，李鑫钢，杜启云.含酚废水治理技术研究进展［J］. 化工进展,2008，27（2）：231-235.
［2］Lin  S H，Wang  C S. Treatment of high-strength phenolic wastewater by a new two-step method ［J］. Journal of Hazardous Materials,2002，90（2）：205-216.
［3］Radushev A  V，Plotnikov A  V，Tyryshkina V  N. Regeneration methods of decontamination of phenol\|containing waste waters［J］.Theoretical Foundations of Chemical Engineering,2008，42（5）：781-794.
［4］Jiang H，Guo Q X. Comparison of liquid\|liquid extraction system and extraction\|evaporation system for high concentrations of phenolic wastewater ［J］. Journal of Environmental Engineering，2007, 133（2）：198-202.
［5］吴慧英，周万龙，黄晟，等.高浓度含酚含醛废水预处理工艺研究［J］.给水排水,2005,31(12):56-59.
［6］姚琳，于萍，罗运柏，等.酚醛废水预处理工艺优化的试验研究［J］.工业水处理,2002,22(12):21-23.
［7］黄发荣,焦杨声.酚醛树脂及其应用［M］.北京：化学工业出版社，2003：493-495.
［8］赵瑞华，商平.尿素降低甲醛废水COD的实验研究［J］.天津化工，2006,20（4）:59-60.
［9］冯守疆,石元亮,邱慧珍.常压下尿素与醛的适宜反应条件研究［J］.土壤通报，2007,    38(1):206-208.
［10］中华人民共和国国家环境保护标准.HJ503-2009水质.挥发酚的测定4-氨基安替比林分光光度法［S］.环境保护部.北京：中国环境科学出版社，2009.
［11］李玉武，张卓.乙酰丙酮分光光度法测定水性涂料中甲醛及测量不确定度评估［J］.岩矿测试，2007,26（1）:45-50.
［12］吴鸿伟.分光光度法测一次性纸杯浸泡液中残留甲醛的含量［J］.枣庄学院学报，2010,27（5）:72-76.
［13］禄树晖,张艳全,郭如振,等.尿素—甲醛的成环化反应［J］.东北林业大学学报，2008,36（12）:69-70.

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