|本期目录/Table of Contents|

[1]熊芳馨,陈春晓,刘善堂*.硅基上图案化自组装膜的制备及表征[J].武汉工程大学学报,2011,(09):4-8.
　XIONG Fang xin,ZHAO Jing,LIU Shan tang.Preparation and characterization of patterned SAMs on silicon wafer[J].Journal of Wuhan Institute of Technology,2011,(09):4-8.
点击复制

硅基上图案化自组装膜的制备及表征(/HTML)
分享到：

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2011年09期
页码:
4-8
栏目:
化学与化学工程
出版日期:
2011-09-30

文章信息/Info

Title:
Preparation and characterization of patterned SAMs on silicon wafer
文章编号:
16742869(2011)09000403
作者:
熊芳馨; 陈春晓; 刘善堂*
绿色化工过程教育部重点实验室，武汉工程大学化工与制药学院，湖北 武汉 430074
Author(s):
XIONG Fangxin;  ZHAO Jing;  LIU Shantang
Key Laboratory for Green Chemical Process of Ministry of Education,School of Chemical Engineering andPharmacy,
 Wuhan Institute of Technology, Wuhan 430074, China
关键词:
硅基薄膜; 电氧化; 自组装
Keywords:
thin films on silicon wafer;  electrooxidation;  selfassemble
分类号:
Q611.4；Q653
DOI:
-
文献标志码:
AAdoi:10.3969/j.issn.16742869.2011.09.002
摘要:
基底上图案化纳米薄膜的制备在微观结构设计领域有广泛应用，在硅基上制备端基为乙烯基的自组装单层膜，利用铜丝电氧化以及高锰酸钾混合溶液氧化，制备不同端基表面的单、双层自组装膜.采用红外光谱(FTIR)、接触角以及原子力显微镜(AFM)对所制备的薄膜进行表征.红外检测结果表明：乙烯基表面经氧化后转变为羧基表面，氧化前后接触角从58.1°转变为19.9°，说明薄膜的亲水性有明显的变化，原子力显微镜扫描得到薄膜的表面形貌，可观察到不同薄膜表面之间的相位及高度变化.结果表明:自组装技术与电氧化法相结合能够有效地制备出不同性质的图案化表面，以用于未来微纳米器件等领域的研究.
Abstract:
Preparation of patterned SAMs on silicon wafer had a wide range of applications to the microstructure design. In this work, we prepared vinyl terminated selfassembled monolayer on the silicon, which was then employed to prepare different endsurface of singledouble selfassembled monolayers by the combination of copper electrooxidation and mixed solution of potassium permanganate oxidation. The resultant SAMs were characterized within frared spectroscopy (FTIR), contact angle and atomic force microscope (AFM). The FTIR results indicated that the vinyl terminated surface was oxidated to carboxyl terminatedsurface. The contact angle changed from 58.1 ° to 19.9 °showed that the membrane was obviously changed to high hydrophilicity.The morphological structures of SAMs was successfully observed with AFM, which displayed the height and phase differences between the films. The study demonstrates that the combination of selfassembly and electrooxidation can be used to prepare different types of patterned surfaces for micronano devices and other research fields in future.

参考文献/References:

［1］Wang W,Gutu T,Gale D K,et al.SelfAssembly of Nanostructured Diatom Microshells into Patterned ArraysAssisted by Polyelectrolyte Multilayer Deposition and Inkjet Printing ［J］.J Am Chem Soc,2009,131:41784179.
［2］徐常龙，曹小华，柳闽生．自组装单层膜的研究［J］.江西师范大学学报,2009,33(2):170174.
［3］于志伟，苗鸿雁，谈国强，等．自组装单层膜技术制备纳米晶态薄膜［J］.材料科学与化学工程，2008,26(2):316320.
［4］Zachary A,Levin G,Mrksich M.Combining selfassembled monolayers and mass spectrometry for applications in biochips［J］.Annu Rev,2008（1）:767800.
［5］Byun M,Bowden N B,Lin Z.Hierarchically Organized Structures Engineered from Controlled Evaporative SelfAssembly［J］.Nano Lett, 2010，10（8）:31113117.
［6］Fowlkes J D,Kondic L,Diez J,et al. SelfAssembly versus Directed Assembly of Nanoparticles via Pulsed Laser Induced Dewetting of Patterned Metal Films［J］.Nano Lett,2011,11（6）：24782485.
［7］Heo D M,Yang M,Kim H,et al.Tip Dependence of the SelfAssembly in DipPen Nanolithography ［J］.J Phys Chem C,2009,113:1381313818.
［8］Morris C J,Alexander A.Patterning NHSTerminated SAMs on Germanium［J］.Langmuir,2011,27:64866489.
［9］Tucker E Z,Gorman C B.Terminal Alkynes as an Ink or Background SAM in Replacement Lithography:Adventitious versus Directed Replacement［J］.Langmuir,2010,26(18):1502715034.
［10］梁山，陈淼．图案化TiO2薄膜的制备技术［J］.化学进展，2008,20(11):16591664.
［11］谈国强，贺中亮，苗鸿雁，等．自组装制备二氧化铪图案化薄膜［J］.无机化学学报，2009,25(10):18531857.
［12］刘铮铮，王琦，刘鑫，等．自组装单分子膜的末端基团对化学气相沉积铜薄膜的影响［J］.材料科学与工程学报，2008,26(4):545549.
［13］Hoeppener S,Maoz R,Sagiv J. Contact Electrochemical Replication of Electrochemically Printed Monolayer Patterns［J］.Adv Mater,2006,18:12861290.
［14］Wen K,Maoz R,Cohen H,et al.Postassembly Chemical Modification of a Highly Ordered Organosilane Multilayer:New Insights into the Structure,Bonding,and Dynamics of SelfAssembling Silane Monolayers［J］.ACS Nano,2008（2）:579599.
［15］Chowdhury D,Maoz R,Sagiv J.Wetting driven selfassembly as new approach to templateguided fabrication of metal nanopatterns［J］.Nano Lett,2007,7(6):17701778.
［16］Steiner G,Moller H,Savchuk O,et al.Characterisation of ultrathin polymer films by polarisation modulation FTIR spectroscopy［J］.Journal of Molecular Structure,2001，563/564:273277.
［17］McGovern M E,Kallury K  M R, Thompson M. Role of solvent on the silanization of glass with octadecyltrichlorosilane ［J］. Langmuir, 1994, 10(10): 36073614.

相似文献/References:

[1]张珈瑜,杨诗林,崔崇威,等.电化学消毒技术研究进展[J].武汉工程大学学报,2021,43(05):473.[doi:10.19843/j.cnki.CN42-1779/TQ. 202104019]
　ZHANG Jiayu,YANG Shilin,CUI Chongwei,et al.Research Progress in Electrochemical Disinfection Process[J].Journal of Wuhan Institute of Technology,2021,43(09):473.[doi:10.19843/j.cnki.CN42-1779/TQ. 202104019]

备注/Memo

备注/Memo:
-
更新日期/Last Update: