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[1]杨鹏,周浪,李俊,等.PMMA胶体晶体模板法制备SiO2多孔材料[J].武汉工程大学学报,2008,(01):76-79.
　YANG Peng,ZHOU Lang,LI Jun,et al.Synthesis of ordered porous silica using poly(metyl methacrylate) colloid crystal as template[J].Journal of Wuhan Institute of Technology,2008,(01):76-79.
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PMMA胶体晶体模板法制备SiO2多孔材料(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2008年01期
页码:
76-79
栏目:
材料科学与工程
出版日期:
2008-01-30

文章信息/Info

Title:
Synthesis of ordered porous silica using poly
(metyl methacrylate) colloid crystal as template
文章编号:
10044736(2008)01007604
作者:
杨鹏; 周浪; 李俊; 邓仕英; 刘长生
武汉工程大学材料科学与工程学院，湖北 武汉 430074
Author(s):
YANG Peng;  ZHOU Lang;  LI Jun;  DENG Shiying;  LIU Changsheng
School of Materials Science & Engineering, Wuhan Insititute of Techlonogy, Wuhan, 430074，China
关键词:
无皂乳液聚合; 胶体晶体模板; 多孔材料
Keywords:
freeemulsion polymerization; colloidal crystals template; porous materials
分类号:
TQ 31
DOI:
-
文献标志码:
A
摘要:
通过PMMA胶体晶体模板法制备了有序的SiO2多孔材料.首先采用两阶段加料的无皂乳液聚合方法，成功地合成了单分散的甲基丙烯酸改性聚甲基丙烯酸甲酯微球，然后将聚合合成的胶乳在一定温度下蒸发一段时间使单分散微球组装成大面积的有序胶体晶体，再以硅溶胶填充胶体晶体，经干燥后煅烧去掉PMMA胶体晶体模板等过程制备较大面积有序的SiO2多孔薄膜.粒径分析、紫外－可见光透过光谱图分析结果表明：所制备的甲基丙烯酸改性聚甲基丙烯酸甲酯微球为单分散且粒径为250 nm左右.扫描电镜、热失重、红外光谱等分析结果表明： SiO2多孔材料孔洞规则排列、相互连接、较好的复制了胶体晶体的有序结构，孔径分布在250 nm左右.
Abstract:
In this paper, ordered porous silica was prepared by using Poly(Metyl Methacrylate) colloid crystal as template. At first, monodispersed PMMA modified by MAA microspheres ware synthesized by twostage freeemulsion polymerization, and highly ordered colloid crystal template could be obtained by evaporating the latexes at certain temperature for some time, then the silica sol is filled between the gap of colloid crystals. The latex sphere was removed by calcinations and ordered porous silica film was obtained. The analysis of latex particles size and Uvvis Spectrum indicated that PMMA modified by MAA microspheres ware monodispersed and the particles size was about 250 nm. SEM, TG, IR show that the distribution of pores was regular and the colloid crystal, material was better reconstructed and the pore size of SiO2 porous materials is about 250 nm.

参考文献/References:

［1］Velev O D, Tessier P M, Lenhoff A M, et al. A class of porous metallic nanostructures［J］.Nature,1999,401:508.
［2］Zakhido A A,Baughman R H. Zafar L, et al. Carbon structures with three dimensional periodicity at optical wavelengths［J］.Science, 1998, 282:897901.
［3］Johnson S A,Ollivier P J,Mallouk T E.Ordered mesoporous polymers of tunable pore size from colloidal silica templates［J］. Science, 1998, 283:962965.
［4］Andreas Stein.Sphere templating methods for periodic porous solid［J］. Microporous and Macroporous Materials,2001,4445:227229.
［5］容建华，杨振忠，齐凯，等，二氧化硅模板技术制备三维有序聚苯乙烯孔材料［J］.科学通报，2000，45（15）：16271630.
［6］阎卫东，李丹，容建华,等.二氧化硅胶体晶模板技术制备间规聚苯乙烯有序孔材料［J］.高等化学学报，2002，23:330332.
［8］杨振忠，齐凯，容建华，等，模板技术合成有序介孔/大孔二氧化硅［J］.科学通报，2001，46（16）:13491352.

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备注/Memo

备注/Memo:
收稿日期：20070621
基金项目：国家自然科学基金（50343018），国家高新技术863计划（2003AA302330），湖北省自然科学基金(2002AC006)
作者简介：杨鹏 （1981），男，湖北黄冈人，硕士研究生. 研究方向:功能高分子材料.
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