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[1]尹传奇,冯权武,陈瑶.过渡金属钌配合物催化氢化CO2生成甲酸的反应[J].武汉工程大学学报,2008,(01):1-06.
　YIN Chuan qi,FENG Quan wu,CHEN Yao.Hydrogenation of CO2 to formic acidcatalyzed by transition metal Ru(Ⅱ) complexes[J].Journal of Wuhan Institute of Technology,2008,(01):1-06.
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2008年01期
页码:
1-06
栏目:
化学与化学工程
出版日期:
2008-01-30

文章信息/Info

Title:
Hydrogenation of CO2 to formic acidcatalyzed by transition metal Ru(Ⅱ) complexes
文章编号:
10044736(2008)01000106
作者:
尹传奇; 冯权武; 陈瑶
武汉工程大学化工与制药学院，绿色化工过程省部共建教育部重点实验室，
湖北省新型反应器与绿色化学工艺重点实验室，湖北 武汉 430074
Author(s):
YIN Chuanqi;  FENG Quanwu;  CHEN Yao
School of Chemical Engineering and Pharnacy, Wuhan Institute of Technology;
Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Key Lab of
Novel Reactror and Green Chemical Technology, Wuhan 430074, China
关键词:
过渡金属二价钌配合物; Ru—H键; 甲酸根配合物; 催化氢化
Keywords:
transition metal Ru (Ⅱ) complexes;  RuH bond;  formate complexes;  catalytic hydrogenation
分类号:
O 626.11； TQ: 032.41
DOI:
-
文献标志码:
A
摘要:
催化氢化CO2 生成甲酸是固定二氧化碳生成C1有机物的重要反应之一，其中过渡金属二价钌配合物催化氢化CO2生成甲酸的反应引起了人们的极大兴趣.对含手臂胺配体、三甲基膦配体和Tp［tris(pyrazolyl)borate］配体的二价钌配合物催化氢化CO2生成甲酸的机理分别进行了讨论.
Abstract:
Catalytic hydrogenation of CO2 to formic acid is one of the reactions of CO2 fixation to form C1 organic compounds. Among these reactions, CO2 hydrogenation to formic acid catalyzed by transition metal Ru (Ⅱ) complexes remains an area of interest. The catalytic mechanisms involved Ru (Ⅱ) complexes containing pendant amine ligand, trimethyl phosphine ligand and Tp ［tris(pyrazolyl)borate］ ligand are discussed, respectively.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：20071024
基金项目：湖北省自然科学基金(No. 2006ABA282)、湖北省教育厅基金(No.D200615005)资助项目
作者简介：尹传奇（1966），男，鄂州市人，副教授，硕士，研究方向：过渡金属配合物的催化反应研究.
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